Ultrathin limit and dead-layer effects in local polarization switching of BiFeO 3
Publication Type
Journal Article
Authors
Maksymovych, P., M. Huijben, M. Pan, S. Jesse, N. Balke, Y.-H. Chu, H.J. Chang, A.Y. Borisevich, A.P. Baddorf, G. Rijnders, D.H.A. Blank, Ramamoorthy Ramesh, S.V. Kalinin
DOI
Abstract
Using piezoresponse force microscopy in an ultrahigh vacuum, polarization switching has been detected and quantified in epitaxial BiFeO 3 films from 200 to about 4 unit cells thick. Local remnant piezoresponse was utilized to probe both ferroelectric properties and effects of imperfect electrical contacts. It was found that the shape of electromechanical hysteresis loops is strongly influenced by an extrinsic dielectric gap, primarily through the suppressing effect of the depolarizing field on the spontaneous polarization in the ultrathin films. Furthermore, statistical analysis of the hysteresis loops has revealed lateral variation of the extrinsic dielectric gap with sub-10-nm resolution. Robust and reproducible ferroelectric properties of nanoscale BiFeO 3 indicate its potential for nanoscale applications in information storage and spintronics. © 2012 American Physical Society.
Journal
Physical Review B - Condensed Matter and Materials Physics
Volume
85
Year of Publication
2012
ISSN
10980121
Notes
cited By 40